氨基硅油是有机硅油中的重要品种，氟原子的引入是提高氨基硅油性能的有效手段。本文简述了含氟丙烯酸酯单体的合成、氨基硅油的接枝改性方法。通过Michael加成接枝氟单体所得最终改性氨基硅油乳液具有良好的防水、防油、耐黄变及稳定性能。

Amino silicone oil is an important variety of organic silicone oil. The introduction of fluorine atom is an effective method to improve the performance of amino silicone oil. In this paper, the synthesis of fluorinated acrylate monomer and graft modification of amino silicone oil were described. The grafting of fluorine monomer modified amino silicone oil emulsion by Michael addition. And Modified amino silicone oil emulsion has a good waterproof, oil proof performance, yellowing resistance property and emulsion stability.

先用开环聚合的方法制备具有氨基侧链的聚硅氧烷氨基硅油，再用甲基丙烯酸三氟乙酯与其侧链上的氨基进行加成反应，得到具有一定疏水性的含氟改性氨基硅油，然后用三乙醇胺对纳米ZnO改性，并将其与改性氨基硅油偶联，最后对纯棉织物进行整理并对其各项性能进行测试。结果表明：合成的改性含氟氨基硅油在保持织物白度与改善柔软性的同时，可提高疏水性和导热性。

Polyorganosiloxane with amino side chain was prepared by ring opening polymerization. Fluori?nated amino- silicon oil with hydrophobicity was obtained by addition reaction of amino group on its side chain and trifluoroethyl methacrylate. And then coupled with nano- zinc oxide, which was modified by triethanol?amine. The cotton fabric treated with modified amino- silicon oil was tested. The results indicated that both of heating conductivity and hydrophobic property of the finished fabric were improved significantly as wel as the whiteness and softness were maintained simultaneously.

以3-氨丙基甲基二乙氧基硅烷、二甲基二甲氧基硅烷为原料制得氨基硅油；以十三氟辛醇、衣康酸等为原料制得衣康酸双（十三氟辛基）酯；分别采用衣康酸双（十三氟辛基）酯、丙烯酸十三氟辛酯与氨基硅油中的伯氨基发生加成反应，制得2种含氟烯酸酯改性氨基硅油，并将其应用于涤纶织物的增深整理。研究了衣康酸双（十三氟辛基）酯改性氨基硅油中氟的质量分数和氨基的质量分数及整理工艺对涤纶织物增深整理效果的影响。衣康酸双（十三氟辛基）酯改性氨基硅油中增加氟的质量分数有利于增深率的提高，而增加氨基的质量分数却导致增深效果降低；丙烯酸十三氟辛酯改性氨基硅油对涤纶织物增深整理的最佳工艺条件为：整理剂浓度30 g/L，焙烘温度160℃，焙烘时间2 min，增深提升率达19.40%。两种改性氨基硅油对涤纶织物均有较好的增深作用。

Amino functional silicone fluid was prepared with 3-amino propyl methyldiethoxysilane and dimethyl dimethoxy silane as the starting materials. Meanwhile,bis(1H,1H,2H,2H-tridecafluorooctyl)meth-ylenesuccinate was prepared with 13 fluoro octanol and itaconate as the starting materials. Then 2 kinds of flu-oroalkyl modifying amino functional silicone fluid were obtained by reacting bis(1H,1H,2H,2H-tridecafluo-rooctyl)methylenesuccinate and 1H,1H,2H,2H-tridecafluorooctyl-1-acrylate with amino functional silicone fluid. The products were applied for darkening finishing on polyester fabrics. The effects of mass fraction of fluorine and amino in bis(1H,1H,2H,2H-tridecafluorooctyl)methylenesuccinate modified amino functional silicone fluid and its finishing technology on the deepening of the polyester fabric finishing were investigated. Results show that increasing the fluorine content in bis(1H,1H,2H,2H-tridecafluorooctyl)methylenesuccinate modified amino functional silicone fluid c

以合成的丙烯酸乳液为基础，与氨基硅油共混制备印花色浆，探索最佳印花工艺。通过各因素的讨论，得出最佳印花工艺为：印花（涂料6％，粘合剂30％，增稠剂PFT8％，氨基硅油5％，蒸馏水X）→烘干（80℃，3min）→焙烘（200℃，2．5min）。通过以上工艺条件对涤棉印花，其干湿摩擦牢度得到了明显的改善。

Based on the synthesis of acrylic latex, the printing paste was prepared mixed with amino-silicone to explore the best printing process. The optimum printing condition is obtained through variety factor investigation as follow: printing (pigment 6%, binder 30%, thickener PFT 8%, amino silicone oil 5%, distilled water X)→drying (80℃,3 min)→baking (200℃,2.5 min). The dry and wet rubbing fastness improved significantly through the above process conditions for polyester cotton blend printing fabric.

以α,ω-二羟基聚二甲基硅氧烷(WS-62M),N-β-氨乙基-γ-氨丙基甲基二甲氧基硅烷(DL-602),单端环氧聚醚(X-O9)为主要原料,合成了一系列聚醚改性氨基聚硅氧烷,探讨了最佳改性条件,并考查了DL-602用量[n(X-O9)∶n(DL-602)]对聚醚改性氨基硅油乳液性能及其应用性能的影响。结果表明,以异丙醇作溶剂,偶联剂用量为11%,n(DL-602)∶n(X-O9)=1∶3,80℃下反应4 h为最佳反应条件;所制聚醚改性氨基硅油乳液稳定性好,用该乳液整理的织物其白度有所提高,硬挺度和悬垂系数有所下降。

α, ω-dihydroxypolydimethylsiloxane (WS-62M),N-β-aminoethyl-γ-aminopropyl methyl dimethoxysilane (DL-602) and Single-ended epoxy polyether (X-09) were used as the raw materials to synthesize a series of polyether modified amino polysiloxane.The modifying process was optimized and the influence of n(X-09):n(DL-602) on polyether modified amino polysiloxane properties was investigated. It was found that the polyether modified amino polysiloxane emulsion had a good stability,which was prepared under the following process:isopropanol was used as the solvent,the coupling agent content was 11%, n(X-09):n(DL-602)=3:1 and reacting at 75℃~80℃for 4 h.The fabrics treated with this kind of emulsion had a promoted whiteness, a decreased stiffness and a decreased drape coefficient.