目的 制备一种固态胺纤维并试验其在CO2含量低于1%时的吸附再生性能.方法 以3种市售平均直径分别为10.4 μm,12.0 μm,15.6 μm的聚丙烯腈纤维(PAN)为基体,通过两步法制备出PAN-聚乙烯亚胺(PEI)固态胺纤维(PAN-PEI);用酸碱滴定法测定了PAN-PEI纤维的胺基含量,用扫描电子显微镜和红外光谱仪表征了纤维的表面微观形貌和官能团结构.结果 在气压100 kPa,温度25.0℃,相对湿度80%,CO2起始浓度1.0%,纤维含水量100%条件下,30 min内测得3种不同直径(从小到大)PAN-PEI纤维在CO2终浓度为0.70%、0.74%与0.75%时的CO2吸附量分别为225、175和160 g/kg;100℃水蒸气再生5 min,循环吸附再生500次,纤维的再生效率为93.2%.结论 制备的PAN-PEI纤维在CO2含量低于1%时,吸附再生性能较好,有望应用于密闭空间中CO2的清除.
Objective To prepare a kind of solid amine fiber and test its properties of CO2 adsorption and desorption.Methods PAN-PEI solid amine fibers were prepared by grafting PEI (polyethleneimine) on three types of commercial hydrolyzed PAN (polyacrylonitrile) fibers with average fiber diameters of 10.4 μm,12.0 μm,and 15.6 μm.The amine contents of PAN-PEI fibers were measured with acid-base titration,the morphology and functional groups of fibers were determined by SEM and FTIR.Results The CO2 sorption amounts of the PAN-PEI fibers (in the fiber diameter increase order) were 225 g/kg,175 g/kg and 160 g/kg respectively in 30 min,under the condition of 100 kPa pressure,25.0 ℃ temperature,80% relative humidity,1.0% CO2 concentration,and 100% water content.The final concentration of CO2 was 0.7%,0.74% and 0.75% respectively.The regeneration efficiency of the fiber was 93.2% through 500 times of adsorption-regeneration by 100 ℃ water steam in 5 min.Conclusion The adsorption a