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双语推荐:表面状态

为研究表面形貌对表面润湿性和抗附着性能的影响,采用激光刻蚀技术制备点阵微结构和仿生贝壳表面网格微结构,将SiO2纳米粒子涂覆在微结构上制备微纳结构。研究表明,Ti6Al4V合金表面经激光刻蚀后由亲水变为超亲水状态。经低表面能修饰后,点阵微结构表面符合Wenzel模式的疏水状态,而网格微结构表面符合Wenzel模式的超疏水状态。在点阵和网格微结构上涂覆SiO2形成微纳结构表面均符合Cassie模式的超疏水状态,且网格结构表面的接触角更大,滚动角更小。浅海挂板实验显示,微生物粘膜附着量由多至少的顺序为:超亲水状态的点阵微结构表面亲水的抛光表面超亲水状态的仿生网格微结构表面符合Cassie模式的超疏水表面
In order to study the impacts of the surface pattern on its wettability and antifouling performance,la-ser etching technique was used to build dot micro-structure and shell surface like grid micro-structure,and the nano-SiO2 powders were coated on the micro-structures to build micro-nano structures.It was shown that after laser etching,Ti6Al4V alloy surface change from hydrophilic state to super hydrophilic one.Trough low sur-face energy modification,the dot micro structure surface was in hydrophobic state that was in accordance with Wenzel model,while the grid micro structure surface was in super hydrophobic state that was in accordance with Wenzel model.The surfaces with the micro-nano structure formed both by coating the nano-SiO2 on the dot or grid micro-structures were both in super hydrophobic state that were in accordance with Cassie model. The grid structure surfaces have greater contact angles and smaller roll angles.Sea-side exposure test showed that the order of the surfaces

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采用极化曲线技术和扫描电镜结合能谱分析,对供货状态和打磨光滑状态的钢筋在混凝土氯离子侵蚀过程中的腐蚀行为进行了研究。通过不同浸泡时间,试样获得了不同的自腐蚀电位及自腐蚀电流密度,分析了不状态试样的表面形貌。结果表明,由于钢筋表面状态不同,钢筋在混凝土中的不同阶段表现出不同的电化学行为。在初期无氯离子的条件下,不同表面状态的钢筋表面钝化膜的稳定性不同,而随着氯离子在混凝土中的入侵,两种钢筋的腐蚀速率也存在很大的差异。结合表面状态分析表明,供货状态钢筋在混凝土氯离子入侵过程中比打磨光滑状态钢筋更易发生腐蚀。
The corrosion behavior of reinforced steel with different surface states in steel bar immersed in simulated solution containing Cl- was investigated by electrochemical measurements,scanning electron microscopy with energy dispersive X-ray spectrometer (SEM/EDX).The changes of corrosion potential and corrosion current density of reinforced steel with the immersion time were obtained,and the morphology of samples with different surface states was analyzed.The results show that the corrosion behavior of reinforced concrete was different in different immersion stages.The stability of passive film formed on the polished steel was better than that of as-supplied steel at the initial stage was when Cl- did not reach the surface of steel.The corrosion rate of as-supplied steel was larger than that of polished steel with the increase of Cl- ions on the surface of steel due to the rough surface caused by thermal oxidation in manufacture process.

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利用疏水/超疏水表面获得滴状冷凝进而提高冷凝器传热系数是目前冷凝器强化传热的重要方法。然而,由于冷凝形成的液滴呈黏性极强的Wenzel状态,在重力作用下很难脱落,使得冷凝传热性能尤其在低冷凝负荷时并不能得到显著提高。研究表明:对粗糙表面施加垂直振动,可观察到其表面上液滴浸润状态的转变。今利用聚二甲基硅氧烷(PDMS)为基底采用光刻技术制备了方柱状和方孔状粗糙表面,对振动作用下 Wenzel 状态液滴的浸润状态转变特性进行了对比研究。结果表明,在一定的频率和振幅下,微方柱状表面的 Wenzel 状态液滴可以发生向 Cassie 状态转变,而方孔状表面的液滴则依然保持Wenzel状态。分析认为,在振动作用下粗糙表面Wenzel液滴能否向Cassie状态转变和其表面微观几何结构密切相关,气液固界面三相接触线的连续性是影响液滴浸润状态转变的重要指标,结合表面物理化学和液滴动力学,建立了物理模型对该现象进行了分析。
Using hydrophobic or superhydrophobic surfaces for forming droplet condensation is an important approach to enhance heat transfer in condensers. However, the condensed droplets appearing on the rough surfaces are in Wenzel state. They can hardly be removed from the surfaces, which is detrimental to heat transfer, especially when the loading of a condenser is low. The transition between the Wenzel and Cassie wetting regimes has been previously observed for droplets on a superhydrophobic surface when the surface is vibrating vertically. In this work, the surfaces with square-post and square-pore were prepared respectively on the polydimethyl-siloxane (PDMS) substrate by using photolithography techniques. The wetting transition of the vibrated droplets on the surfaces was analyzed. The experimental results show that the Wenzel state droplets on the surface with square-post can change into Cassie state during vibration at certain frequencies. However, the Wenzel state droplets on

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以亲水性微观粗糙表面上不同几何形貌及分布的微柱阵列为对象,讨论了液滴在亲水性粗糙表面上的润湿过程以及润湿状态的转变阶段。从能量角度分别考察了微观粗糙结构几何形貌及分布、微柱几何参数、固体表面亲水性、接触角滞后作用等因素对液滴润湿状态转变的影响规律。研究发现:在亲水粗糙表面,正方形微柱呈正六边形阵列分布时,液滴更容易形成稳定的Cassie状态,或者液滴仅发生Cassie状态向中间浸润状态的转变;与此同时,减小微柱间距、增大方柱宽度或圆柱直径、增大微柱高度、增强固体表面的亲水性将有利于液滴处于稳定的Cassie状态,或阻止润湿状态向伪-Wenzel或Wenzel状态转变;然而,当液滴处于Cassie状态时,较小的固-液界面面积分数或减弱固体表面亲水性能均有利于增大液滴的表观接触角,因此在亲水表面设计粗糙结构时应综合考虑润湿状态稳定性和较大表观接触角两方面因素;此外,接触角滞后作用对于液滴状态的稳定性以及疏水性能的实现具有相反作用的影响。研究结果为液滴在亲水表面获得稳定Cassie状态的粗糙结构设计方法提供了理论依据。
The wetting process and the wetting state transition stages are studied on hydrophilic rough surfaces covered with microscale pillar arrays of different geometrical morphologies and distributions. The effects of geometrical morphology, distribution, parameters, hydrophilicity, and contact angle hysteresis of pillar arrays on wetting state transition are analyzed by an energy method. The results indicate that on the hydrophilic rough surface covered with hexagonal arrays of square pillars, the water droplet tends to stay in a stable Cassie state, or the wetting state transits only from a Cassie state to an intermediate state. Moreover, smaller pillar interval, larger square pillar width or diameter of cylinder, higher pillar height, strong hydrophilicity are beneficial to the stability of Cassie state, therefore, the wetting state could be prevented from transforming to pseudo-Wenzel state or Wenzel state. However, smaller area fraction of solid-liquid interface under the water drop and

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航天器与等离子体环境中的电子、离子相互作用,表面将出现充放电效应,对航天器产生负面影响.表面充电电位对充放电影响至关重要.综合考虑等离子体中粒子质量、温度及密度,二次电子效应及非偏置固体的运动速度等因素,基于气体动理论,利用粒子的麦克斯韦速度分布函数理论推导得出等离子体环境中非偏置固体表面充电电位一般表达式.分析了等离子体以及非偏置固体特殊状态下的表达式及一般状态下的表达式,总结出不同等离子环境、不同运动状态下的表面充电规律.
Within the plasma environment of spacecraft, the interaction between electrons and ions may cause surface charging and discharg-ing and may degrade the performance of spacecraft. The charging potential is a key factor for discharging process. By considering the comprehensive effects of particle mass, temperature, density of plasma, secondary electrons and the velocity of unbiased solid, a general equation of surface charging potential of unbiased solid has been derived using Maxwell velocity distribution function. The expressions under some special and general conditions have been also analyzed. The surface charging and discharging properties are summarized under different plasma environment and motion states of unbiased solid.

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以聚二甲基硅氧烷(PDMS)基底采用光刻蚀技术制备了微方柱结构粗糙表面。采用高速摄影对液滴在垂直振动作用下的动态浸润状态进行了图像采集。通过对水滴振动过程中的动态浸润特性分析,研究了粗糙表面水滴的Wenzel-Cassie浸润状态转变特征。结果表明,对于一定尺寸的Wenzel状态水滴,只有当施加的振动能量超过某一阈值时,微方柱粗糙表面Wenzel状态液滴才可以发生向Cassie状态的完全转变,且存在发生Wenzel-Cassie浸润转变的阈值范围;此外,当外加振动频率和液滴固有频率一致时,即在共振频率时,液滴发生Wenzel-Cassie状态转变需要的能量最小。外加振动频率偏离液滴固有频率越远,发生Wenzel-Cassie状态转变需要的能量最大。基于表面化学和振动力学理论,建立了液滴发生Wenzel-Cassie转变时的物理模型。
Superhydrophobic surfaces have aroused great attention for promising applications, e.g., enhanced heat transfer. The rough surface of square-shaped pillars was prepared from the polydimethyl-siloxane (PDMS) substrate by using photolithography technique. Based on the analysis of dynamic wetting characteristics of water droplets during vertical vibration, the Wenzel-Cassie wetting transition on the rough surface was studied with experimental and theoretical techniques. The experimental results showed that the Wenzel state droplets on the square-shaped pillars rough surface could change to the Cassie state when forced vibration frequency and amplitude were in the threshold range. When the eigenfrequency of the droplet was in accordance with forced vibration frequency, that is to say, at the resonance frequency, the forced vibration amplitude for Wenzel-Cassie wetting transition reached the lowest value. When forced vibration frequency was far from eigenfrequency, vibration amplitude was g

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利用聚二甲基硅氧烷(PDMS)为基底采用光刻技术制备了微方柱状超疏水表面,分析了冷凝条件下超疏水表面液滴的冷凝生长特征,发现液滴的生长过程可分为微液滴成核冷凝独立生长、冷凝微液滴合并生长以及大液滴生长3个阶段。超疏水表面初始合并的液滴呈Wenzel-Cassie状态和Wenzel状态,随着冷凝液滴的成长,液滴的液-固接触面积与粗糙结构表面的表观面积之比f随着冷凝液滴尺寸的增大而增大,Wenzel-Cassie状态向完全Wenzel状态转变。最后分析了超疏水性破坏的原因。
The square-shaped pillars superhydrophobic surfaces were prepared with the polydimethyl -siloxane ( PDMS) sub-strate using photolithography techniques .The growth dynamics of water droplets condensed on a superhydrophobic geometrically patterned surface were studied .Experimental results show that there are three steps during the growing of the water droplets on the superhydrophbic patterned surface at low temperature .The first step is that the small droplets grow lonely .The second step is that the small droplets coalesce and the last step is that the big droplets grow .Furthermore, the droplets on the surface are Wen-zel-Cassie or Wenzel state at first .With increasing of the size of the droplets , the fraction of the solid-liquid contact area and the solid apparent area increases .The Wenzel-Cassie state of the droplets on the superhydrophobic surfaces transform into the Wenzel state when the size of the droplets increase .

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介绍了研究石英中杂质赋存状态的重要性以及原子力显微镜在石英表面分析中的应用,结果通过原子力显微镜我们能够看到石英表面颗粒分布均匀,结构致密,颗粒没有大尺度的起伏等表面结构,并且利用它高的分辨率得到了石英表面纳米级别的微观形貌,为后续的确定杂质赋存状态做了准备。
The importance of studying the impurity occurrence state and the application of atomic force microscopy(AFM) in surface analysis of quartz were introduced.The quartz grains were well distributed and had compact structure and non-large scale fluctuation.The nanometer level micro-morphology was obtained using high resolution of AFM,which made preparation for the subsequent determination of impurities occurrence state.

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为了更加精确地测量附面层流动状态,并验证表面热膜测试技术的可靠性,利用表面热膜测量了低雷诺数定常来流条件下高负荷涡轮叶栅通道内叶片吸力面附面层的流动状态,并与表面静压实验测得结果进行对比。结果表明,利用表面热膜测得的准壁面剪切力以及相关的统计参数能够准确捕捉到附面层分离泡和转捩的位置,对于高负荷低压涡轮叶型附面层流动测量是可靠有效的。
In order to research boundary layer separation behaviors more accuratly and to prove that the sur-face hot-film testing technique is reliable,a hot-film experimental investigation on steady low Reynolds number boundary layer separation behaviors of the suction surface of a high-loaded low-pressure turbine blade was de-scribed,which was compared with the static pressure experimentation. The experimental results indicate that the quasi-shear stress and the statistical value of the surface hot-film can capture the position of separation bubble and transition accurately. The surface hot-film technique is effective and reliable for measurement on the high-load low-pressure turbine blade.

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研究了 TiO2表面染料的吸附状态不同时,染料敏化太阳能电池(DSC)的光电转换性能,并采用电化学交流阻抗技术(EIS)考察了不同染料吸附状态下DSC中的电子界面复合效应。结果表明,在非饱和吸附染料状态下,通过调整 TiO2薄膜表面染料分子吸附量,可以降低界面电荷复合效应,使电子在 TiO2薄膜的传输过程中寿命增加,从而提高DSC的填充因子。
The photoelectric conversion properties of dye-sensitized solar cells (DSC)with different status of dye adsorption on the TiO2 surface were investigated.The recombination effect of electrons in the DSC under differ-ent status of dye adsorption was characterized by electrochemical impedance spectra (EIS).The results showed a decline of electron recombination at interface under the condition of unsaturated dye adsorption through adj us-ting the dye loading amount on the TiO2 film,which increased the lifetime of electrons transport in the TiO2 film and enhanced the fill factor of the DSC.

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