The properties of a new delocalised E…E bonding(E= ⅤA ,ⅥA elements) in peri-1 ,8-disub-stituted naphthalene derivatives were studied by the electron density topological analysis method .The re-sults predicted the existence of the delocalized bonding of E …E bond for E=O ,S ,Se ,N ,P and As ,in the peri-1 ,8-disubstituted naphthalene derivatives .In total ,chalcogen…chalcogen bonding was stronger than nitrogen…nitrogen bonding .Topological analysis showed that this kind of E …E bonding belonged to weak interaction .The strength of the E…E bonding decreased in the sequence of O ,S ,Se or N ,P ,As .The E…E bonding are electrostatic interactions for E=O ,S ,Se ,N ,and P ,while the As…As bonding has partly cova-lent interaction .