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双语推荐:光刻胶

光刻胶剖面形貌和关键尺寸(CD)是光刻工艺的关键参数,而实际光刻工艺中受到前层次图形的影响,尤其是后端布线工艺受到前面工序高低台阶影响十分严重。文章基于光学干涉原理及King的胶厚理论模型和光刻胶Swing Curve曲线研究了光刻胶跨越高台阶对成像的影响,分析了造成光刻胶剖面和关键尺寸变化的主要原因。一是台阶处衬底的反射影响了光刻胶剖面形貌;二是高台阶处光刻胶厚度比正常厚度变薄导致光刻曝光条件不适用于高台阶处光刻胶。最后通过优化胶厚及增加底部抗反射层有效解决CD差异和改善光刻胶形貌。
Profile and critical dimension are key process data in lithography process which are affected by substrate morphology. The study on photo resist spans high level imaging effects resulting in low optical plastic CD morphology of the main reasons, due to the reflection and bench nearby stepped substrate photo resist thickness change. By selecting the right photo resist thickness and increasing bottom antireflective layer can effectively resolve CD difference and improve photo resist profile.

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提出了铁氧体薄膜器件光刻多次涂胶新工艺,研究了涂覆次数对光刻胶的表面粗糙度、均匀性和厚度的影响。同时结合培烘试验,对一种实际电路基片进行了验证。试验结果表明:随着光刻胶涂覆次数的增加,光刻胶厚度逐渐增大,增加幅度逐渐减小,涂覆光刻胶的表面粗糙度有明显改善,均匀性也逐渐提高。当烘焙温度为50℃、烘焙时间为25min,光刻胶与基底的附着力、感光性和耐腐蚀性均能满足铁氧体器件薄膜电路制作工艺的要求。利用多次涂胶法可有效去除电路手工修补工艺,从而提高铁氧体薄膜器件的电路图形加工质量及效率。
Multiple spin-coating technology was proposed for ferrite film device lithograph, and influence of coating times on the surface rougnness, uniformity and thickness of photo-resist was investigated. At the same time, baking test was conducted on a practical circuit substrate. The experimental results show that, with increasing the number of coating photo-resist, the thickness of photo-resist increases, with a decreased increase amplitude, and both surface roughness and uniformity of photo-resist is improved obviously. When baking at 50℃for 25min, photo-resist adherence to the substrate, photo-sensitivity, and corrosion-resistance of the photo-resist can meet the requirements of thin film circuit production process of ferrite devices. The use of multiple coating can omit circuit manual repairing, resultantly improving the quality and efficiency of the circuit graphics processing of ferrite thin film devices.

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文章研究了在127mm硅片上分别生长金属铝和二氧化硅氮化硅叠两种IC常用材料作为衬底对光刻胶形貌的影响,其造成光刻胶形貌差的原因是金属底部反射率高导致光刻胶侧面曝光和入射光通过二氧化硅氮化硅叠层厚度的光程差正好为光源波长的整数倍,从而导致光刻胶底部干涉光同相位。通过增加底部抗反射层和调整最佳膜层厚度解决了在这两种衬底材料下光刻胶形貌差的问题。
The influence of the photo resists cross section on alliums and SiO2 substrate had been investigated. We can get better photo resists cross section by adding bottom arc layer on alliums substrate, if transparent substrate, it can be done by changing the film thickness.

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光刻是利用光化学反应将临时电路图形从掩膜版转移到光刻胶膜上的工艺。影响光刻质量的因素包含光源、掩膜版与光刻胶三部分。其中,掩膜版与光源(光刻机)在日常生产中视为固定不变的因素。相比较而言,光刻胶受曝光条件、显影条件、烘干条件等诸多因素的影响,其性质会有明显变化。本文就光刻胶膜的陡直度(以下简称"陡直度")进行了一系列研究和实验,其最终目的是找到现有条件下提高光刻线条陡直度的方法。
Lithography is a process which uses photochemical reaction to transfer temporary circuit pattern from mask to PR film. The factors that affect the quality of lithography include the UV source, mask and PR. . Among the factors, we treat the mask and the UV source ( aligner) as steady conditions. Only the PR, compared with the other factors, its features can be influenced by changing the pa-rameters of exposure, development, or baking conditions. This paper makes a series of research and experiment for the steepness of PR film in order to find some methods for increasing the steepness of PR film under the existing conditions.

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为降低涂胶工序的生产成本,减少光刻胶的用量,需要在涂胶工艺上不断改进和提高。从原来传统的涂胶工艺到RRC(Reduced Resist Consumption)工艺,能够使光刻胶的用量减少,而随着光刻胶用量的减少,圆片上胶厚的均匀性也在发生剧烈的变化。同时光刻涂胶工序最重要的工艺要求就是胶厚和均匀性,它直接影响着后续曝光工艺的稳定性。在RRC工艺下,通过对喷胶转速、排风、喷胶速率等涂胶参数进行多次试验,最终找出影响胶厚均匀性的参数及其调整方法,来达到工艺要求的胶厚及均匀性,保障工艺生产的稳定性。
Some method had been used to reduce the semiconductor manufacture cost, such as reducing photo resist consumption, which result in the uniformity of photo resist becoming more lager. Photo resist uniformity and thickness are the important process parameter which could influence the quality of exposal process. By changing chuck rotation speed, pump velocity, exhaust, the best process condition for RRC process has been accomplished, the relationship between photo resist uniformity and other process condition has been developed;The photo resist uniformity and thickness can be controlled steadily and make sure the steady of the fab process.

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采用经稀释的光刻胶在喷胶机上对打孔的基片进行了雾化喷涂试验,在通孔结构表面实现了光刻胶的均匀涂覆。在同一基片上选取了十个通孔,采用扫面电镜对基片表面、通孔边缘及通孔侧壁中部和底部四处的光刻胶厚度进行了测量,得到的平均膜厚分别为10.2、8.8、6.1和5.3μm,各处厚度均匀性均小于±10%。
The diluted photoresist was applied in spray coating process on drilled substrate using a spray coating equipm ent. The conform al coating of photoresist layer on through via structure was achieved. Ten through via on the sam e substrate were selected. For each through via,the photoresist layer thickness of substrate surface,through via edge,sidewall center and sidewall bottom were m easured respectively by H ITACHI Scanning E lectron Microscope. The average value of film thickness were 10.2,8.8,6.1 and 5.3μm ,and allthickness uniform ity was less than ±10% .

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采用溶胶凝胶协同自组装与光刻相结合的方法,在光子晶体反蛋白石结构中引入缺陷,通过溶胶凝胶协同自组装方法在硅片上垂直沉积胶体晶体复合薄膜,把BP212正性光刻胶均匀旋涂在复合薄膜上,通过曝光、显影等光刻工艺,把掩膜版图案复制在复合薄膜上,用此样品再次垂直沉积一层复合薄膜,使图案被复合薄膜覆盖.最后去除胶体微球与光刻胶图案,从而在反蛋白石结构中引入缺陷,用扫描电子显微镜对样品进行表征.分析了光刻胶图案对胶体微球排列的影响.
By applying planar lithography and sol-gel co-assembly methods, the designed two-dimensional defects were intro-duced in inverse opal films. Composite colloidal crystal films which can turn into inverse opal films after calcination were fabricated by sol-gel co-assembly method. Photoresist patterns produced by planer lithograph either on silicon or composite colloidal film/silicon substrate were used as the sacrificial structure to form the designed defects. To form the embedded defects in inverse opal films, a layer of composite colloidal crystal film was assembled on the photoresist patterns. After calcination, both PS spheres and photoresist were removed, and the designed defects were introduced in the inverse opal films. Influence of the photoresist patterns on self-assembled PS particles was also characterized.

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为了在锗晶体光坯上制作出满足要求的码盘图案,分别采用正性光刻胶和负性光刻胶,先镀膜后照相和先照相后镀膜的工艺路线进行工艺实验,并对实验结果进行分析,得出结论:用负性光刻胶按先照相后镀膜的工艺路线为锗晶体光码盘分划制作工艺的最佳方案。实验结果表明:加工出的图案明暗对比度大、边缘不均匀性小于0.008mm,可实际应用于锗晶体上分划图案的制作。
In order to process code disc pattern on the Ge crystal base met the needs ,we did the technological experiments ,through adopting the positive photoresist and negative photoresist , in the technological ways that coating before exposure and exposure before coating ,respective‐ly .We analyzed the measurement results ,and came to the conclusion that the optimum matc‐hing scheme of reticle pattern processing technology for Ge crystal optical encoder was adop‐ting the negative photoresist in accordance with the exposure before coating .Experimental re‐sults show that the finished graphic pattern has obvious contrast ,the asymmetry distribution of edge is lower than 0 .008 mm .It can be applied to the manufacture of the reticle pattern on Ge base .

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光栅在通信、光存储及光谱分析领域具有广泛的应用。对超声辅助UV-LIGA技术制备光栅的可行性进行了试验研究。试验中两次利用超声的特殊效应,实现不同的辅助功能。1)采用超声辅助显影,通过改善光刻胶模沟槽内的物质传输,提高光刻胶模结构的显影效率和显影质量。2)在后烘之后、显影之前对光刻胶结构进行超声处理,通过在空气中对光刻胶模结构进行超声处理,有效降低SU-8胶模在电铸过程中的溶胀。选取优化的工艺参数,采用侧向冲液电铸方式,获得了镍基光栅。
The grating is widely used in the fields of communication, optical storage and spectroscopy. In this paper, the experiment of grating preparation by ultrasonic-assisted UV-LIGA is conducted. Different auxiliary functions are realized by using special ultrason-ic effects twice. Firstly, the ultrasonic-assisted process is used to improve the substances transmission in the photoresist mold groove, the developing efficiency and quality. Secondly, the ultrasonic-assisted developing is introduced between the processes of post-baking and developing, and the structure of photoresist mold is subjected to the ultrasonic treatment in the air, then the swel ing of plastic mold of SU-8 is reduced evidently in the electroforming process. The process parameters are optimized and the lateral red liquid electroforming way is adopted. Final y, a thickness of 65μm nickel based grating is successful y prepared.

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通过对液晶显示器制造过程中的关键工序---光刻胶涂布工艺、原理进行分析,对光刻胶涂布设备参数进行调整等,为生产LCD提高合格率提供参考。
Based on the key working procedure in the process of LCD m anufacture -photoresist coating process, principle analysis, adjust photoresist coating equipm ent param eters etc, provide reference for production im prove the qualified rate of LCD .

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